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METHYL 2-(4-BROMOPHENYL)-2,2-DIMETHYLACETATE
- Name: METHYL 2-(4-BROMOPHENYL)-2,2-DIMETHYLACETATE
- CAS: 154825-97-5
- Purity: 99%
Details
Factory supply METHYL 2-(4-BROMOPHENYL)-2,2-DIMETHYLACETATE 154825-97-5 with sufficient production capacity
- Molecular Formula: C11H13BrO2
- Molecular Weight: 257.127
- Appearance/Colour: Colourless oil
- Vapor Pressure: 0.00209mmHg at 25°C
- Refractive Index: 1.522
- Boiling Point: 290.322 °C at 760 mmHg
- Flash Point: 129.382 °C
- PSA： 26.30000
- Density: 1.337 g/cm3
- LogP: 2.89970
METHYL 2-(4-BROMOPHENYL)-2,2-DIMETHYLACETATE(Cas 154825-97-5) Usage
InChI:InChI=1/C11H13BrO2/c1-11(2,10(13)14-3)8-4-6-9(12)7-5-8/h4-7H,1-3H3
154825-97-5 Relevant articles
DIHYDROPYRIMIDINE COMPOUNDS AND USES THEREOF IN MEDICINE
-
Paragraph 00262, (2019/05/10)
Provided herein are a dihydropyrimidine ...
Dihydropyridine compound and application thereof to drugs
-
Paragraph 0649-0652, (2019/05/08)
The invention relates to a dihydropyridi...
Dihydropyrimidine compound and uses of dihydropyrimidine compound in drugs
-
Paragraph 0636; 0640; 0641; 0642, (2019/01/16)
The present invention relates to a dihyd...
DIHYDROPYRIMIDINE COMPOUNDS AND USES THEREOF IN MEDICINE
-
Paragraph 00250, (2019/01/17)
Provided herein are a dihydropyrimidine ...
154825-97-5 Process route
-
-
67-56-1
methanol
-
-
32454-35-6
2-(4-bromophenyl)-2-methylpropionic acid
-
-
154825-97-5
methyl 2-(4-bromophenyl)-2,2-dimethylacetate
| Conditions | Yield |
|---|---|
|
With
sulfuric acid; acetonitrile;
at 80 - 85 ℃;
for 16 - 18h;
|
98%
|
|
With
sulfuric acid;
In
toluene;
at 63 - 67 ℃;
for 16h;
Industry scale;
|
79%
|
|
With
sulfuric acid;
In
toluene;
at 63 - 67 ℃;
for 16h;
Industry scale;
|
79%
|
-
-
83636-46-8
methyl 2-(4-bromophenyl)propanoate
-
-
74-88-4
methyl iodide
-
-
154825-97-5
methyl 2-(4-bromophenyl)-2,2-dimethylacetate
| Conditions | Yield |
|---|---|
|
methyl 2-(4-bromophenyl)propanoate;
With
n-butyllithium; diisopropylamine;
In
tetrahydrofuran;
at -78 - 0 ℃;
for 0.75h;
methyl iodide;
In
tetrahydrofuran;
at -78 - 20 ℃;
for 1.5h;
With
potassium tert-butylate;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 1.5h;
|
|
|
methyl 2-(4-bromophenyl)propanoate;
With
lithium hexamethyldisilazane;
In
tetrahydrofuran; toluene;
at -78 ℃;
for 0.5h;
methyl iodide;
In
tetrahydrofuran; toluene;
at 0 - 20 ℃;
for 1.5h;
|
80 mg
|
|
methyl 2-(4-bromophenyl)propanoate;
With
lithium hexamethyldisilazane;
In
tetrahydrofuran; toluene;
at -78 ℃;
for 0.5h;
methyl iodide;
In
tetrahydrofuran; toluene;
at -78 - 20 ℃;
for 1.5h;
With
potassium tert-butylate;
In
tetrahydrofuran; toluene;
at 0 - 20 ℃;
for 1.5h;
|
80 mg
|
|
methyl 2-(4-bromophenyl)propanoate;
With
sodium hexamethyldisilazane;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 1h;
Inert atmosphere;
methyl iodide;
In
tetrahydrofuran;
at 20 ℃;
Inert atmosphere;
|
154825-97-5 Upstream products
-
41841-16-1
(4-bromo-phenyl)-acetic acid methyl ester
-
74-88-4
methyl iodide
-
83636-46-8
methyl 2-(4-bromophenyl)propanoate
-
1634-04-4
tert-butyl methyl ether
154825-97-5 Downstream products
-
154825-93-1
4-(4-Hydroxy-1-butynyl)-α,α-dimethylbenzeneacetic acid methyl ester
-
32454-35-6
2-(4-bromophenyl)-2-methylpropionic acid
-
897935-07-8
5-[1-(4-bromophenyl)-1-methylethyl]-1H-1,2,4-triazol-3-amine
-
32454-37-8
2,2-dimethyl-2-(4-bromophenyl)ethanol
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