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Details
Buy Good Quality VINYL ACRYLATE 2177-18-6 with a minimum purity of 99%
- Molecular Formula: C5H6 O2
- Molecular Weight: 98.1014
- Vapor Pressure: 53.7mmHg at 25°C
- Melting Point: -81.9°C
- Refractive Index: n20/D 1.432(lit.)
- Boiling Point: 91.5°Cat760mmHg
- Flash Point: 13.5°C
- PSA： 26.30000
- Density: 0.936g/cm3
- LogP: 0.85910
VINYL ACRYLATE(Cas 2177-18-6) Usage
|
Hazard |
A poison by ingestion. Low toxicity by inhalation. A severe skin and eye irritant. |
InChI:InChI=1/C5H6O2/c1-3-5(6)7-4-2/h3-4H,1-2H2
2177-18-6 Relevant articles
Reusable rhodium catalyst for the selective transvinylation of sp2-C linked carboxylic acid
Jiang, Ruihang,Chen, Zhangpei,Zhan, Kun,Liu, Lei,Zhou, Junjie,Ai, Yongjian,Li, Shuang,Bao, Hongjie,Hu, Ze'nan,Qi, Li,Wang, Jingting,Sun, Hong-bin
, p. 3279 - 3282 (2018/07/21)
The vinyl benzoate derivatives were succ...
METHOD FOR PRODUCING CYCLIC UNSATURATED COMPOUND
-
Page/Page column 75-76, 84-85; 91; 93, (2008/06/13)
The present invention provides a method ...
Process for Preparing Vinyl Carboxylates
-
Page/Page column 6, (2009/01/24)
The present invention relates to a proce...
Transvinylation process for the preparation of thermally labile vinyl compounds and for vinyl compounds prepared from thermally labile acids
-
, (2008/06/13)
A process for the transvinylation of a v...
2177-18-6 Process route
-
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74-85-1
ethene
-
-
79-10-7
acrylic acid
-
-
547-65-9
α-methylene-γ-butyrolactone
-
-
2177-18-6,30811-69-9
vinyl acrylate
| Conditions | Yield |
|---|---|
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
1-methyl-pyrrolidin-2-one;
at 50 - 60 ℃;
for 4 - 36h;
under 1838.93 - 2942.29 Torr;
Product distribution / selectivity;
|
5.7 - 65 %Chromat.
4.8 - 18 %Chromat. |
|
palladium diacetate;
In
2-n-butyl-4-(hydroxymethyl)imidazole;
at 50 ℃;
for 16h;
under 367.786 Torr;
Product distribution / selectivity;
|
0.5 %Chromat.
1.3 %Chromat. |
|
With
4-methoxy-phenol; p-benzoquinone;
palladium 10% on activated carbon;
at 80 ℃;
for 16h;
under 2574.5 Torr;
Product distribution / selectivity;
|
6.0 %Chromat.
11.8 %Chromat. |
|
With
oxygen; 4-methoxy-phenol;
palladium 10% on activated carbon;
In
cyclohexane;
at 80 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
3.5 %Chromat.
2.3 %Chromat. |
|
With
oxygen; 4-methoxy-phenol;
palladium 10% on activated carbon;
In
1-methyl-pyrrolidin-2-one;
at 80 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
6.3 %Chromat.
4.6 %Chromat. |
|
With
oxygen; 4-methoxy-phenol;
palladium 10% on activated carbon;
at 80 ℃;
for 16h;
under 2868.73 - 2942.29 Torr;
Product distribution / selectivity;
|
4.9 - 15 %Chromat.
6.6 - 19 %Chromat. |
|
With
oxygen; 4-methoxy-phenol;
Pd/Te/C (2%);
at 80 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
5.1 %Chromat.
3.2 %Chromat. |
|
With
manganese(IV) oxide; oxygen; p-benzoquinone;
palladium diacetate;
In
1-methyl-pyrrolidin-2-one;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
2.4 %Chromat.
2.7 %Chromat. |
|
With
manganese(IV) oxide; oxygen; p-benzoquinone;
palladium diacetate;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
3.8 - 6.8 %Chromat.
3.0 - 30 %Chromat. |
|
With
manganese(IV) oxide; oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
1-methyl-pyrrolidin-2-one;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
4.5 - 29 %Chromat.
3.1 - 6.6 %Chromat. |
|
With
oxygen; copper diacetate; benzene-1,2-diol;
palladium diacetate;
In
1-methyl-pyrrolidin-2-one;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
23 %Chromat.
12 %Chromat. |
|
With
oxygen; p-benzoquinone;
palladium diacetate;
In
1-methyl-pyrrolidin-2-one;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
3.6 - 26 %Chromat.
3.9 - 10 %Chromat. |
|
With
oxygen; p-benzoquinone; calcium carbonate;
palladium diacetate;
In
2-n-butyl-4-(hydroxymethyl)imidazole;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
44 %Chromat.
8.3 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
2-n-butyl-4-(hydroxymethyl)imidazole;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
33 %Chromat.
2.2 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
dichloromethane;
at 50 ℃;
for 36h;
under 1838.93 Torr;
Product distribution / selectivity;
|
0.5 %Chromat.
8.3 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
N,N-dimethyl-formamide;
at 50 ℃;
for 16 - 36h;
under 1838.93 - 2942.29 Torr;
Product distribution / selectivity;
|
2.2 - 24 %Chromat.
3.7 - 5.9 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
1,2-dimethoxyethane;
at 50 ℃;
for 36h;
under 1838.93 Torr;
Product distribution / selectivity;
|
1.7 %Chromat.
5.3 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
acetonitrile;
at 50 ℃;
for 36h;
under 1838.93 Torr;
Product distribution / selectivity;
|
1.0 %Chromat.
10 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
ISOPROPYLAMIDE;
at 50 ℃;
for 16 - 36h;
under 1838.93 - 2942.29 Torr;
Product distribution / selectivity;
|
3.1 - 47 %Chromat.
3.9 - 18 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
benzonitrile;
at 50 ℃;
for 16 - 36h;
under 1838.93 - 2942.29 Torr;
Product distribution / selectivity;
|
5.8 - 18 %Chromat.
2.9 - 42 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
acetic acid butyl ester;
at 50 ℃;
for 36h;
under 1838.93 Torr;
Product distribution / selectivity;
|
2.0 %Chromat.
12 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
desipramine;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
48 %Chromat.
8.6 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
NCP;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
50 %Chromat.
5.5 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
11 %Chromat.
35 - 36 %Chromat. |
|
With
oxygen; sodium 2-propenoate; p-benzoquinone;
tetrakis(acetonitrile)palladium(II) tetrafluoroborate;
In
1-methyl-pyrrolidin-2-one;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
5.6 %Chromat.
42 %Chromat. |
|
With
H5PV2Mo10O40; oxygen; sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
2-n-butyl-4-(hydroxymethyl)imidazole;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
7.1 %Chromat.
1.7 %Chromat. |
|
With
oxygen; lithium carbonate; p-benzoquinone;
palladium diacetate;
In
2-n-butyl-4-(hydroxymethyl)imidazole;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
37 %Chromat.
5.1 %Chromat. |
|
With
sodium 2-propenoate; p-benzoquinone;
palladium diacetate;
In
1-methyl-pyrrolidin-2-one;
at 50 ℃;
for 16h;
under 367.786 Torr;
Product distribution / selectivity;
|
36 %Chromat.
5.2 %Chromat. |
|
With
oxygen;
palladium diacetate;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
0.4 %Chromat.
2.4 %Chromat. |
|
With
oxygen; sodium 2-propenoate;
palladium diacetate;
In
1-methyl-pyrrolidin-2-one;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
16 %Chromat.
5.1 %Chromat. |
|
With
oxygen; sodium 2-propenoate;
palladium diacetate;
In
dimethyl sulfoxide;
at 50 ℃;
for 16h;
under 2942.29 - 4781.22 Torr;
Product distribution / selectivity;
|
0.2 - 0.7 %Chromat.
0.1 - 0.5 %Chromat. |
|
With
oxygen; sodium 2-propenoate;
palladium dichloride;
In
ISOPROPYLAMIDE;
at 50 ℃;
for 16h;
under 2942.29 Torr;
Product distribution / selectivity;
|
1.4 - 2.2 %Chromat.
12 - 15 %Chromat. |
-
-
5309-67-1
vinyl β-chloropropionate
-
-
2177-18-6,30811-69-9
vinyl acrylate
| Conditions | Yield |
|---|---|
|
With
sodium methylate;
In
methanol;
at 50 - 55 ℃;
|
98%
|
2177-18-6 Upstream products
-
108-05-4
vinyl acetate
-
79-10-7
acrylic acid
-
1119-20-6
divinylmercury
-
5309-67-1
vinyl β-chloropropionate
2177-18-6 Downstream products
-
30934-97-5
2,2-dimethoxyethanol
-
2499-59-4
octyl acrylate
-
3530-36-7
2-phenylethyl acrylate
-
5321-77-7
(formylmethyl)mercury chloride
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